|
|
H+ + L-pyrroline-5-carboxylate + malonyl-CoA + H2O <=> (2S,5S)-5-carboxymethylproline + CoA + CO2
|
2.3.1.226
carboxymethylproline synthase
|
–
|
|
BRENDA:
BR50641
KEGG:
R10485
MetaCyc:
RXN-8947
SABIO-RK:
7117
|
|
|
|
electron-transfer_quinone + L-proline <=> electron-transfer_quinol + H+ + L-pyrroline-5-carboxylate
|
1.5.5.2
proline dehydrogenase
|
–
|
|
MetaCyc:
RXN-14903
|
|
|
|
(3R,5S)-carbapenam-3-carboxylate + acceptor <=> (5R)-carbapen-2-em-3-carboxylate + reduced_acceptor
|
not assigned
|
–
|
|
MetaCyc:
RXN-8952
|
|
|
|
(3S,5S)-carbapenam_3-carboxylate + 2-oxoglutarate + O2 <=> (5R)-carbapen-2-em-3-carboxylate + succinate + CO2 + H2O
|
1.14.20
1.14.20.3
(5R)-carbapenem-3-carboxylate synthase
|
–
–
|
|
BRENDA:
BR50588
KEGG:
R10415
MetaCyc:
RXN-8949
|
|
|
|
(3S,5S)-carbapenam_3-carboxylate <=> (3R,5S)-carbapenam-3-carboxylate
|
not assigned
|
–
|
|
MetaCyc:
RXN-8950
|
|
|
|
(2S,5S)-5-carboxymethylproline + ATP <=> H+ + (3S,5S)-carbapenam_3-carboxylate + AMP + diphosphate
|
6.3.3.6
carbapenam-3-carboxylate synthase
|
–
|
|
BRENDA:
BR50731
KEGG:
R10556
MetaCyc:
RXN-8948
|
|